Volume 8; Issue 1

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Organometallics
Volume 8; Issue 1

Organometallics

Volume 8; Issue 1

1

Reactions of dinuclear metal carbonyl .alpha.-diimine complexes with alkynes. Part 3. Reversible C-N bond formation and fission between an .alpha.-diimine ligand and a methyl propynoate molecule on a dinuclear iron carbonyl moiety. X-ray crystal structures of Fe2(CO)6{(i-Pr)NC(H)C(H)N(i-Pr)C(H)CC(O)OMe} and Fe2(CO)4{(i-Pr)NC(H)C(H)N(i-Pr)C(H)CC(O)OMe}

Muller, Fred., Van Koten, Gerard., Vrieze, Kees., Heijdenrijk, Dick., Krijnen, Bert B., Stam, Casper H.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1000 KB

english, 1989

2

Chemistry of (.mu.-dithio)bis(tricarbonyliron), an inorganic mimic of organic disulfides. 3. Reaction with low-valent metal compounds and some interesting isolobal analogies involving the products

Cowie, Martin., DeKock, Roger L., Wagenmaker, Timothy R., Seyferth, Dietmar., Henderson, Richard S., Gallagher, Michael K.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.88 MB

english, 1989

3

Quantitative analysis of ligand effects. Part 3. Separation of phosphorus(III) ligands into pure .sigma.-donors and .sigma.-donor/.pi.-acceptors. Comparison of basicity and .sigma.-donicity

Rahman, M. Matiur., Liu, Hong Ye., Eriks, Klaas., Prock, Alfred., Giering, Warren P.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 924 KB

english, 1989

4

Versatile behavior of hydrido monometallic or heterobimetallic carbonyl anions toward dichlorophosphines and 1,1-dichlorodiphosphines

Westermann, Hermann., Nieger, Martin., Niecke, Edgar., Majoral, Jean Pierre., Caminade, Anne Marie., Mathieu, Rene., Irmer, Erhard.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 739 KB

english, 1989

5

Metal alkoxides: models for metal oxides. 14. Carbonylation of an ethylidyne-capped tritungsten alkoxide cluster to form W3(.mu.-CMe)(OCHMe2)9(CO)2: preparation, properties, and structure

Chisholm, Malcolm H., Folting, Kirsten., Huffman, John C., Klang, Jeffrey A., Streib, William E.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 615 KB

english, 1989

6

Photolysis of acetyltetracarbonylcobalt(I) in low-temperature matrixes: unusual behavior for a coordinatively unsaturated intermediate

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 676 KB

english, 1989

7

Isometallocenes. 2. (Aminoarene)(tetramethylcyclobutadiene)cobalt(I) hexafluorophosphates

Cook, Malcolm R., Pauson, Peter L.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 378 KB

english, 1989

8

Aliphatic versus aromatic carbon-hydrogen activation and the x-ray crystal structure of [IrH(H2O)(7,8-benzoquinolinato)(PPh3)2]SbF6

Lavin, Maryellen., Holt, Elizabeth M., Crabtree, Robert H.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 683 KB

english, 1989

9

A comparison of the structures of exo- and endo-(.eta.5-cyclopentadienyl)(.eta.3-2-methylallyl)ruthenium carbonyl

Hsu, Leh Yeh., Nordman, Christer E., Gibson, Dorothy H., Hsu, Wen Liang.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 500 KB

english, 1989

10

Reactions of dinuclear metal carbonyl .alpha.-diimine complexes with alkynes. Part 2. Selective coupling of an .alpha.-diimine ligand and CO and methyl propynoate molecules to give Fe2(CO)n{(R)N:C(H)C(H)N(R)C(O)C(H):CC(O)OMe}, containing a flyover-type ligand and showing a reversible CO-induced metal-metal bond fission with x-ray crystal structures (n = 5, R = i-Pr; n = 6, R = c-hex)

Muller, Fred., Van Koten, Gerard., Vrieze, Kees., Heijdenrijk, Dick.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 993 KB

english, 1989

11

Synthesis, structure, and reactivity of bridging halide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)]2X+ BF4-. Preferential binding of one enantiomer of halide complexes (.eta.5-C5H5)Re(NO)(PPh3)(X) by the chiral Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+

Winter, Charles H., Arif, Atta M., Gladysz, J. A.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.39 MB

english, 1989

12

Electrochemical and chemical reduction of titanocene dihalides - an ESR study

Samuel, Edmond., Vedel, Jacques.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 638 KB

english, 1989

13

Synthesis and chemistry of thiagermiranes

Tsumuraya, Takeshi., Sato, Sadao., Ando, Wataru.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 904 KB

english, 1989

14

Biomimetic organometallic chemistry. Regio- and stereoselectivity in the hydroxylation reaction of cyclohexyltriphenyltin with metalloporphyrins as the biomimetic catalysts and iodosylbenzene as the oxygen transfer agent

Fish, Richard H., Price, Robert T.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 557 KB

english, 1989

15

Synthesis, structure, and reactions of heterobinuclear .mu.-methylene complexes

Mackenzie, Peter B., Coots, Robert J., Grubbs, Robert H.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 980 KB

english, 1989

16

Addition of scandium-hydrogen, scandium-carbon, and scandium-nitrogen bonds to coordinated carbon monoxide. Structure of a methylscandoxycarbene derivative of cobalt

St. Clair, Martin A., Santarsiero, Bernard D., Bercaw, John E.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 797 KB

english, 1989

17

Kinetics and mechanism of the thermal decomposition of (E)- and (Z)-1,1,2,3-tetramethylsiletane

Conlin, Robert T., Namavari, Mohammad., Chickos, James S., Walsh, Robin.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.01 MB

english, 1989

18

Structural features in electron-deficient (.eta.-pentamethylcyclopentadienyl)titanium-diene complexes and their catalysis in the selective oligomerization of conjugated dienes

Yamamoto, Hitoshi., Yasuda, Hajime., Tatsumi, Kazuyuki., Lee, Keonil., Nakamura, Akira., Chen, Jie., Kai, Yasushi., Kasai, Nobutami.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.87 MB

english, 1989

19

Synthesis, structure, and reactions of rhenium aminocarbyne complexes formed from [ReCl2(CNR)3(PMePh2)2]+ (R = tert-Bu or Me) cations under reductive coupling conditions

Warner, Steve., Lippard, Stephen J.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.19 MB

english, 1989

20

Synthetic approaches to the chiral, pyramidal, transition-metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+X-. Generation, characterization, and reactions of a dichloromethane adduct

Fernandez, Jesus M., Gladysz, J. A.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 2.18 MB

english, 1989

21

Isolation and x-ray structure of an intermediate in the reaction of (.mu.-S)2Fe2(CO)6 with thiolates: the [(.mu.-S)(.mu.-S2-tert-Bu)Fe2(CO)6]- ion

Wu, Xintao., Bose, K. S., Sinn, E., Averill, B. A.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 435 KB

english, 1989

22

Bis-ortho-chelated arylcopper compounds. Synthesis and x-ray crystal structure of Cu4Br2[C6H3(CH2NMe2)2-o,o']2

Wehman, Erik., Van Koten, Gerard., Erkamp, Cornelis J. M., Knotter, D. Martin., Jastrzebski, Johann T. B. H., Stam, Casper H.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 782 KB

english, 1989

23

Heterometallic alkylidyne clusters: natural products as sources of chirality

Clark, Debbie T., Sutin, Karen A., McGlinchey, Michael J.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 785 KB

english, 1989

24

Regio- and stereospecific conversion of chromium dienes into olefins via anionic allyl complexes

Wink, Donald J., Wang, Nai Fang., Springer, James P.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 451 KB

english, 1989

25

Electrochemistry of dinuclear, thiolato-bridged transition-metal compounds. Part 4. Electrochemical activation of dinuclear thiolato-bridged molybdenum complexes [Mo2Cp2(CO)4(.mu.-SR)2]0/2+ (R = Me, Ph) toward carbonyl substitution reactions. Electrochemical and chemical syntheses of substituted derivatives. The x-ray crystal structure of [Mo2Cp2(CO)3(MeCN)(.mu.-SPh)2](BF4)2

El Khalifa, Moulay., Gueguen, Monique., Mercier, Rene., Petillon, Francois Y., Saillard, Jean Yves., Talarmin, Jean.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.22 MB

english, 1989

26

Masthead

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 131 KB

english, 1989

27

Rhenium carbonyl phosphine dinitrogen complexes (.eta.5-C5Me5)Re(CO)(PR3)(N2)

Klahn, A. Hugo., Sutton, Derek.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.28 MB

english, 1989

28

A double intramolecular ring metalation: formation, spectroscopic characterization, and molecular structure of (C5Me3(CH2)2)Ta(H)2(PMe3)2

Carter, Steven T., Clegg, William., Gibson, Vernon C., Kee, Terence P., Sanner, Robert D.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 461 KB

english, 1989

29

Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR')4(W.tplbond.W) complexes. 2. Metal-carbon bond homolysis and competitive alkane and dihydrogen eliminations in double .alpha.-hydrogen activation processes

Chisholm, Malcolm H., Eichhorn, Bryan W., Huffman, John C.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.60 MB

english, 1989

30

Tungsten-carbon, carbon-carbon and carbon-hydrogen bond activations in the chemistry of W2R2(OR')4(W.tplbond.W) complexes. 3. Competitive .alpha.-hydrogen versus .beta.-hydrogen eliminations and ethylene-to-acetylene hydrogen transfers

Chisholm, Malcolm H., Eichhorn, Bryan W., Huffman, John C.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.29 MB

english, 1989

31

Mechanism of the cross-coupling reaction of phenyl iodide and methylmagnesium iodide catalyzed by trans-PdPh(I)(PEt2Ph)2

Ozawa, Fumiyuki., Kurihara, Kunihiko., Fujimori, Mizue., Hidaka, Takahiro., Toyoshima, Tsukasa., Yamamoto, Akio.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.15 MB

english, 1989

32

The first salt- and solvent-free monocyclopentadienyl lanthanide dialkyl complex. X-ray structure determinations of La(.eta.5-C5Me5)[CH(SiMe3)2]2 and of its tetrahydrofuran adduct: compounds containing agostic silicon-carbon bonds

Van der Heijden, Harry., Schaverien, Colin J., Orpen, A. Guy.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 588 KB

english, 1989

33

Electrochemistry of dinuclear, thiolato-bridged transition-metal compounds. 5. The electrochemical behavior of [Mo2Cp2(CO)3(L)(.mu.-SR)2]2+ (L = MeCN, t-BuNC; R = Me, Ph)

Gueguen, Monique., Petillon, Francois Y., Talarmin, Jean.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 908 KB

english, 1989

34

Synthesis and spectral characterization of a series of iron and ruthenium benzylidene complexes, Cp(CO)(L)M:CH(C6H4R)+ (M = Fe, Ru; L = CO, PPh3; R = p-H, p-F, p-CH3, p-OCH3). Barriers to aryl rotation and benzylidene transfer reactions

Brookhart, M., Studabaker, William B., Humphrey, M. Beth., Husk, G. Ronald.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.09 MB

english, 1989

35

Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR')4(W.tplbond.W) complexes. 1. Alkyne-promoted metal-to-metal alkyl migrations, W.tplbond.W/C.tplbond.C bond metathesis, and metallacyclopropene formation

Chisholm, Malcolm H., Eichhorn, Bryan W., Folting, Kirsten., Huffman, John C.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 2.21 MB

english, 1989

36

Organometallchemie

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 133 KB

english, 1989

37

Stereoselective trans addition of D2 to the coordinated RN=C(R1)C(H)=NR ligand in FeRu(CO)6(R-DAB;R1,H(6e)) to afford FeRu(CO)6(.mu.,.mu.'-N(R)CR1DCHDN(R)) (R = iso-Pr, R1 = Me, H; R = p-Tol, R1 = H). Kinetic 1H NMR studies of the hydrogenation at hydrogen pressures between 1 and 70 bar. Single-crystal x-ray structure determinations of FeRu(CO)6(.mu.,.mu.'-N(R)CH2CR1HN(R)) (R = iso-Pr and R1 = H, Me)

Zoet, Robert., Elsevier, Cornelis J., Van Koten, Gerard., Versloot, Peter., Vrieze, Kees., Van Wijnkoop, Maarten., Duineveld, Cornelis A., Goubitz, Kees., Heijdenrijk, Dick., Stam, Casper H.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.22 MB

english, 1989

38

Structural consequences of electron-transfer reactions. Part 18. Redox-induced hapticity changes: effect of substituents on arene bending in a series of rhodium complexes

Bowyer, Walter J., Merkert, Jon W., Geiger, William E., Rheingold, Arnold L.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 1.03 MB

english, 1989

39

Synthesis of new monomeric zirconium and hafnium hydride butadiene complexes. The x-ray structure of (.eta.5-cyclopentadienyl)(.eta.4-butadiene)[1,2-bis(dimethylphosphino)ethane]hydridozirconium

Wielstra, Ytsen., Meetsma, Auke., Gambarotta, Sandro.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 292 KB

english, 1989

40

Equilibrium studies of thiophene exchange in (.eta.-thiophene)Ru(.eta.-C5H5)+: a model for thiophene adsorption on hydrodesulfurization catalysts

Hachgenei, Johannes W., Angelici, Robert J.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 548 KB

english, 1989

41

Preparation and x-ray structure of [Cp2Zr(.mu.-I)]2. A thermally unstable zirconium(III) complex

Wielstra, Ytsen., Gambarotta, Sandro., Meetsma, Auke., De Boer, Jan L.

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 283 KB

english, 1989

42

Book Reviews

Journal:

Organometallics

Année:

1989

Langue:

english

Fichier:

PDF, 284 KB

english, 1989