Volume 29; Issue 23

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Organometallics
Volume 29; Issue 23

Organometallics

Volume 29; Issue 23

1

Oxidative Addition of Ethyl Iodide to a Dimethylplatinum(II) Complex: Unusually Large Kinetic Isotope Effects and Their Transition-State Implications

Nabavizadeh, S. Masoud, Habibzadeh, Sepideh, Rashidi, Mehdi, Puddephatt, Richard J.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.53 MB

english, 2010

2

Sterically Hindered Diazabutadienes (DABs): Competing Reaction Pathways with MeLi

Bhadbhade, Mohan, Clentsmith, Guy K. B., Field, Leslie D.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1017 KB

english, 2010

3

Transfer Hydrogenation of Ketones and Catalytic Oxidation of Alcohols with Half-Sandwich Complexes of Ruthenium(II) Designed Using Benzene and Tridentate (S, N, E) Type Ligands (E = S, Se, Te)

Singh, Pradhumn, Singh, Ajai K.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.18 MB

english, 2010

4

Highly Active Single-Component Neutral Nickel Ethylene Polymerization Catalysts: The Influence of Electronic Effects and Spectator Ligands

Mu, Hong-Liang, Ye, Wei-Ping, Song, Dong-Po, Li, Yue-Sheng

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.06 MB

english, 2010

5

Abnormal N-Heterocyclic Carbene Promoted Suzuki−Miyaura Coupling Reaction: A Comparative Study

Xu, Xiangya, Xu, Baochang, Li, Yongxin, Hong, Soon Hyeok

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 939 KB

english, 2010

6

Electrophilic, Ambiphilic, and Nucleophilic C−H Bond Activation: Understanding the Electronic Continuum of C−H Bond Activation Through Transition-State and Reaction Pathway Interaction Energy Decompositions

Ess, Daniel H., Goddard, William A., Periana, Roy A.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 4.51 MB

english, 2010

7

Lanthanide- and Actinide-Mediated Terminal Alkyne Hydrothiolation for the Catalytic Synthesis of Markovnikov Vinyl Sulfides

Weiss, Charles J., Wobser, Stephen D., Marks, Tobin J.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.28 MB

english, 2010

8

Insight into the Steric and Electronic Effects of Ancillary Ligands: Synthesis and Structure−Reactivity Relationship of Well-Defined, Air- and Moisture-Stable (NHC)Pd(sal)Cl Complexes (sal = Salicylaldimine)

Jin, Zhong, Qiu, Ling-Ling, Li, Yan-Qing, Song, Hai-Bin, Fang, Jian-Xin

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.20 MB

english, 2010

9

Synthesis and Characterization of New, Chiral P−N Ligands and Their Use in Asymmetric Allylic Alkylation

Thiesen, Kurtis E., Maitra, Kalyani, Olmstead, Marilyn M., Attar, Saeed

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.31 MB

english, 2010

10

Highly Enantioselective Addition of Dialkylzinc to Trifluoroacetophenones, Catalyzed by 1,2-Diamines. Synthesis of Key Fragments of Inhibitors of the Enzyme 11β-HSD1 and Kinetic Analysis of the Process †

Genov, Miroslav, Martínez-Ilarduya, Jesús M., Calvillo-Barahona, Mercedes, Espinet, Pablo

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 907 KB

english, 2010

11

Regioselective 1,3-Dipolar Cycloaddition Reaction of Azides with Alkoxy Alkynyl Fischer Carbene Complexes

Chakraborty, Amarnath, Dey, Surjendu, Sawoo, Sudeshna, Adarsh, N. N., Sarkar, Amitabha

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 810 KB

english, 2010

12

An Experimental−Theoretical Study of the Factors That Affect the Switch between Ruthenium-Catalyzed Dehydrogenative Amide Formation versus Amine Alkylation

Nova, Ainara, Balcells, David, Schley, Nathan D., Dobereiner, Graham E., Crabtree, Robert H., Eisenstein, Odile

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 2.71 MB

english, 2010

13

Synthesis of Exclusively Centrostereogenic 1,3-Bidentate Ferrocenyldiphosphane Ligands and Their Use in Enantioselective Hydrogenations

Lotz, Matthias, Schuecker, Raffael, Mereiter, Kurt, Knochel, Paul

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 916 KB

english, 2010

14

Nickel(0)-Catalyzed Formation of Oxaaluminacyclopentenes via an Oxanickelacyclopentene Key Intermediate: Me 2 AlOTf-Assisted Oxidative Cyclization of an Aldehyde and an Alkyne with Nickel(0)

Ohashi, Masato, Saijo, Hiroki, Arai, Tomoya, Ogoshi, Sensuke

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 973 KB

english, 2010

15

Alkali Metal Complexes of a tert -Butylphosphine-Bridged Biphenolate Ligand

Hsu, Yu-Lin, Liang, Lan-Chang

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 955 KB

english, 2010

16

Pyridyl Gold(I) Alkynyls: A Synthetic, Structural, Spectroscopic, and Computational Study

Kilpin, Kelly J., Horvath, Raphael, Jameson, Geoffrey B., Telfer, Shane G., Gordon, Keith C., Crowley, James D.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 3.08 MB

english, 2010

17

Derivatization of Niobium Complexes Bearing Imido and Acetophenone Imine Ligands

Neshat, Abdollah, Schmidt, Joseph A. R.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.03 MB

english, 2010

18

Synthesis and Characterization of Silver and Palladium Complexes with Xanthene-Based N-Heterocyclic Carbene−Oxazoline Ligands

Makino, Takeshi, Yamasaki, Ryu, Azumaya, Isao, Masu, Hyuma, Saito, Shinichi

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 2.42 MB

english, 2010

19

Mechanistic Aspects of Nucleophilic Substitution at Half-Sandwich Metal Complexes

Dinda, Shrabani, Sebastian, K. L., Samuelson, Ashoka G.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 3.71 MB

english, 2010

20

Expansion of the Ligand Knowledge Base for Monodentate P-Donor Ligands (LKB-P) †

Jover, Jesús, Fey, Natalie, Harvey, Jeremy N., Lloyd-Jones, Guy C., Orpen, A. Guy, Owen-Smith, Gareth J. J., Murray, Paul, Hose, David R. J., Osborne, Robert, Purdie, Mark

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.28 MB

english, 2010

21

Isopolyoxometalates of Antimony: Arylstibonic Acids [H 8 (RSb) 12 O 28 ] and Derived Dodecanuclear Polyoxostibonates [M 2 H 10− x (RSb) 12 O 30 ] x − , M = Na or K

Nicholson, Brian K., Clark, Christopher J., Wright, Cody E., Groutso, Tania

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 2.76 MB

english, 2010

22

Synthesis of a Thiocarbamoyl Alkylidyne Complex and Caveats Associated with the Use of [Mo(≡CLi)(CO) 2 (Tp)] (Tp = Hydrotris(3,5-dimethylpyrazol-1-yl)borate)

Colebatch, Annie L., Hill, Anthony F., Shang, Rong, Willis, Anthony C.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.94 MB

english, 2010

23

[W(CO)(dppe) 2 ] Cumulenylidene and Acetylide Complexes Accessed via Stannylated Acetylenes and Butadiynes

Semenov, Sergey N., Blacque, Olivier, Fox, Thomas, Venkatesan, Koushik, Berke, Heinz

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 3.01 MB

english, 2010

24

Photophysical and Theoretical Studies of Ruthenium(II)−Acetylide and −Cyanide Complexes with Aromatic Diimine and Trithiacyclononane

Wong, Chun-Yuen, Lai, Lo-Ming, Chan, Siu-Chung, Tai, Lai-Hung

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 2.52 MB

english, 2010

25

Facile Insertion of N 2 O into Metal−Carbon Bonds of Metallocene Allyl Complexes to Form (RN 2 O) − Ligands

Demir, Selvan, Montalvo, Elizabeth, Ziller, Joseph W., Meyer, Gerd, Evans, William J.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 759 KB

english, 2010

26

Kinetics and Thermodynamics of the Monomer−Dimer Equilibria of Dialkoxydibutylstannanes

Whittleton, Sarah R., Rolle, Alfred J., Boyd, Russell J., Grindley, T. Bruce

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 2.61 MB

english, 2010

27

Addition of Enamines or Pyrroles and B(C 6 F 5 ) 3 “Frustrated Lewis Pairs” to Alkynes

Dureen, Meghan A., Brown, Christopher C., Stephan, Douglas W.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 2.80 MB

english, 2010

28

Bis(dimethylsilyl)amide Complexes of the Alkaline-Earth Metals Stabilized by β-Si−H Agostic Interactions: Synthesis, Characterization, and Catalytic Activity

Sarazin, Yann, Roşca, Dragoş, Poirier, Valentin, Roisnel, Thierry, Silvestru, Anca, Maron, Laurent, Carpentier, Jean-François

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.87 MB

english, 2010

29

A Novel Bis(phosphido)pyridine [PNP] 2− Pincer Ligand and Its Potassium and Bis(dimethylamido)zirconium(IV) Complexes

Winston, Matthew S., Bercaw, John E.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 4.52 MB

english, 2010

30

Ferrocenyl-polyphenylenes: Toward Metallo-organic Polyaromatics

Roberts, Dilwyn J., Gregg, Daniel J., Fitchett, Chris M., Draper, Sylvia M.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 921 KB

english, 2010

31

Diphosphine Mobility at a Binuclear Metal Center: A Concerted Double Trigonal-Twist in Bis(dithiolate) Complexes [M 2 (CO) 4 (μ-dppm){μ-S(CH 2 ) n S}] (M = Fe, Ru; n = 2, 3)

Hogarth, Graeme, Kabir, Shariff E., Richards, Idris

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.38 MB

english, 2010

32

A Heteroleptic Palladium(II) Complex Containing a Bidentate Carbene/Amido Ligand and 3-(Trifluoromethyl)-5-(2-pyridyl)pyrazolate: Fast Catalyst Activation in the Heck Coupling Reaction

Sie, Ming-Han, Hsieh, Yuan-Hsin, Tsai, Yi-Hua, Wu, Jia-Rong, Chen, Shih-Jung, Kumar, P. Vijaya, Lii, Jenn-Huei, Lee, Hon Man

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.20 MB

english, 2010

33

Introduction to the Review by Wright, Turrell, and Pickett in This Issue of Organometallics , and a Tip-of-the-Hat to Arnold (Arnie) Rheingold

Gladysz, John A.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 2.82 MB

english, 2010

34

The Third Hydrogenase: More Natural Organometallics

Wright, Joseph A., Turrell, Peter J., Pickett, Christopher J.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 3.19 MB

english, 2010

35

The Reaction of Carbon Dioxide with Palladium−Allyl Bonds

Wu, Jianguo, Green, Jennifer C., Hazari, Nilay, Hruszkewycz, Damian P., Incarvito, Christopher D., Schmeier, Timothy J.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.85 MB

english, 2010

36

Synthesis, Structural Characterization, and Preliminary Reactivity Profile of a Series of Monocyclopentadienyl, Monoacetamidinate Titanium(III) Alkyl Complexes Bearing β-Hydrogens

Trunkely, Emily F., Epshteyn, Albert, Zavalij, Peter Y., Sita, Lawrence R.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.33 MB

english, 2010

37

Synthesis of Ferrocenyl Diphosphine Ligands: Substitution of α-Methoxy or α-Dimethylamino Groups by Phosphines. Retention versus Inversion: A Stereochemical Study

Schuecker, Raffael, Weissensteiner, Walter, Mereiter, Kurt, Lotz, Matthias, Spindler, Felix

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.54 MB

english, 2010

38

Half-Sandwich (η 6 -Arene)iron(II) Dinitrogen Complexes Bearing a Disilaferracycle Skeleton as a Precursor for Double Silylation of Ethylene and Alkynes

Sunada, Yusuke, Imaoka, Tsuyoshi, Nagashima, Hideo

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1006 KB

english, 2010

39

Congested Cyclometalated Platinum(II) Ditopic Frameworks and Their Phosphorescent Responses to S-Containing Amino Acids

Tong, Wah-Leung, Chan, Michael C. W., Yiu, Shek-Man

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.85 MB

english, 2010

40

Orthometalated Amino-Carbene Derivatives of Iridium via Anilines and Terminal Alkynes

Kumaran, Elumalai, Sridevi, Venugopal Shanmugham, Leong, Weng Kee

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.03 MB

english, 2010

41

Structural Flexibility of Bis(phenoxyimine) Titanium Complexes in the Early Stages of Olefin Polymerization Process: A DFT Study

Flisak, Zygmunt, Suchorska, Patrycja

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 833 KB

english, 2010

42

Dehydrocoupling of Organosilanes with a Dinuclear Nickel Hydride Catalyst and Isolation of a Nickel Silyl Complex

Smith, Erin E., Du, Guodong, Fanwick, Phillip E., Abu-Omar, Mahdi M.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.02 MB

english, 2010

43

Revisiting the Metathesis of 13 C-Monolabeled Ethane

Maury, Olivier, Lefort, Laurent, Vidal, Véronique, Thivolle-Cazat, Jean, Basset, Jean-Marie

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 756 KB

english, 2010

44

Protonation of Cobalt−Allene Constitutional Isomers: Highly Selective Formation of Cobalt−Allyl and Oxacobaltacyclopentadiene Complexes

O’Connor, Joseph M., Chen, Ming-Chou, Holland, Ryan L.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.23 MB

english, 2010

45

Thermolysis of Half-Sandwich Vanadium(V) Imido Complexes to Generate Vanadium(III) Imido Species via a Vanadium(IV) Intermediate

Batinas, Aurora A., Dam, Jeroen, Meetsma, Auke, Hessen, Bart, Bouwkamp, Marco W.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 927 KB

english, 2010

46

Mechanistic Insights into C−S Cross-Coupling Reactions Catalyzed by Nickel Bis(phosphinite) Pincer Complexes

Zhang, Jie, Medley, Christopher M., Krause, Jeanette A., Guan, Hairong

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.27 MB

english, 2010

47

N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl 2 Si═NR

Ghadwal, Rajendra S., Roesky, Herbert W., Schulzke, Carola, Granitzka, Markus

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 862 KB

english, 2010

48

Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes

Dureen, Meghan A., Brown, Christopher C., Stephan, Douglas W.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 3.50 MB

english, 2010

49

Efficient Concatenation of C═C Reduction, C−H Bond Activation, and C−C and C−N Coupling Reactions on Osmium: Assembly of Two Allylamines and an Allene

Baya, Miguel, Esteruelas, Miguel A., Oñate, Enrique

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.31 MB

english, 2010

50

Dirhodium Complexes Bridged by Bis(diphenylphosphino)phthalazine (PNNP Ph ): Central Ring Size and Charge Effects As Compared with the Pyrazolate Derivative (PNNP Py )

Yamaguchi, Takafumi, Koike, Takashi, Akita, Munetaka

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.34 MB

english, 2010

51

Experimental and Theoretical Study of a Tungsten Dihydride Silyl Complex: New Insight into Its Bonding Nature and Fluxional Behavior

Ray, Mausumi, Nakao, Yoshihide, Sato, Hirofumi, Sakaki, Shigeyoshi, Watanabe, Takahito, Hashimoto, Hisako, Tobita, Hiromi

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 7.96 MB

english, 2010

52

Alkynyl Selenolate Complexes of Iron, Nickel, and Molybdenum

Caldwell, Lorraine M., Hill, Anthony F., Hulkes, Alexander G., McQueen, Caitlin M. A., White, Andrew J. P., Williams, David J.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 959 KB

english, 2010

53

Hydroquinoid Chromium Complexes Bearing an Acyclic Conjugated Bridge: Chromium-Templated Synthesis, Molecular Structure, and Haptotropic Metal Migration

Hegele, Peter, Santhamma, Bindu, Schnakenburg, Gregor, Fröhlich, Roland, Kataeva, Olga, Nieger, Martin, Kotsis, Konstantinos, Neese, Frank, Dötz, Karl Heinz

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 3.11 MB

english, 2010

54

Organometallic Macrocyclic Chemistry. 8.(1) An Unusual Metallacycle Derived from Phosphine−Alkynyl Thioether Coupling

Hill, Anthony F., Niess, Barbara, Schultz, Madeleine, White, Andrew J. P., Williams, David J.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 910 KB

english, 2010

55

Synthesis, Spectroscopic Characterization, and Cytotoxic Evaluation of Pentasubstituted Ruthenocenyl Esters

Micallef, Leanne S., Loughrey, Bradley T., Healy, Peter C., Parsons, Peter G., Williams, Michael L.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.02 MB

english, 2010

56

A Cobaltocenium Complex of Dibenzo[ c,g ]fluorenide and Its Structural and Electrochemical Properties

Pammer, Frank, Sun, Yu, Sieger, Monika, Fiedler, Jan, Sarkar, Biprajit, Thiel, Werner R.

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.18 MB

english, 2010

57

Unprecedented CpLi Ammoniacates

Michel, Reent, Herbst-Irmer, Regine, Stalke, Dietmar

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 867 KB

english, 2010

58

Pressurized Sample Infusion for the Continuous Analysis of Air- And Moisture-Sensitive Reactions Using Electrospray Ionization Mass Spectrometry

Vikse, Krista L., Woods, Michael P., McIndoe, J. Scott

Journal:

Organometallics

Année:

2010

Langue:

english

Fichier:

PDF, 1.98 MB

english, 2010