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A Range of Spin-Crossover Temperature T1/2>300 K Results from Out-of-Sphere Anion Exchange in a Series of Ferrous Materials Based on the 4-(4-Imidazolylmethyl)-2-(2-imidazolylmethyl)imidazole (trim) Ligand, [Fe(trim)2]X2 (X=F, Cl, Br, I): Comparison of Experimental Results with Those Derived from Density Functional Theory Calculations
Gilles Lemercier, Nicolas Bréfuel, Sergiu Shova, Juliusz A. Wolny, Françoise Dahan, Marc Verelst, Hauke Paulsen, Alfred X. Trautwein, Jean-Pierre TuchaguesVolume:
12
Année:
2006
Langue:
english
Pages:
12
DOI:
10.1002/chem.200501249
Fichier:
PDF, 228 KB
english, 2006