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Formation of a heterobimetallic compound by reductive elimination of methane and oxidative cleavage of an aryl-phosphorus bond in reaction of trans-MeIr(CO)[P(p-tolyl)3]2 with HMoCp(CO)3: Crystal and molecular structures of CpMo(CO)2[.mu.-P(p-tolyl)2]Ir(p-tolyl)[P(p-tolyl)3](CO)2 (Mo-Ir) and CpMo(CO)2[.mu.-P(p-tolyl)2]Ir(H)[P(p-tolyl)3](CO)2 (Mo-Ir)
McFarland, Jeffrey M., Churchill, Melvyn Rowen., See, Ronald F., Lake, Charles H., Atwood, Jim D.Volume:
10
Langue:
english
Journal:
Organometallics
DOI:
10.1021/om00056a024
Date:
October, 1991
Fichier:
PDF, 1001 KB
english, 1991