Chiral Ansa Zirconocene Compounds with [Me 2 Si] and [Me 4 Si 2 ] Bridges and with tert -Butyl Ring Substituents:  Synthesis and Structural Characterization of the Racemo Complexes r ac - [Me 2 Si(C 5 H 2 -2,4-Bu t2 ) 2 ]ZrCl